A numbered kit is premixed, so you should almost never need to mix anything. That is the honest headline, and most articles on this subject bury it under a wheel diagram. Grisaille is the extreme version of that idea — value alone, with the color left out entirely.
There are three situations where mixing genuinely comes up. Everything below is about those, plus the small amount of color theory that actually helps you paint the canvas better.

The three times you might mix
1. You have run out of a color. Most likely on a large canvas with a lot of sky or a single dominant color. Extra paint sets exist for most designs and are the right answer. If you cannot wait, matching against the reference print with the pots you have is possible but rarely exact.
2. A pot has cured and cannot be rescued. Same situation, same answer.
3. You are deliberately going beyond the design — softening a transition, adding a highlight. This is a choice rather than a necessity, and it is worth knowing that the design's color relationships were resolved by the original artist. Change one and the neighbours often want changing too.
If you do have to match a color
- Start from the lighter color and add the darker, a little at a time. Dark pigment is far stronger — a drop of black into white moves it a long way; white into black barely registers. This is the mistake everyone makes once.
- Mix more than you need. Reproducing a mixed color a second time is much harder than making enough the first time.
- Test on a spare corner and let it dry. Acrylic dries slightly darker than it looks wet. Judging a match while wet will give you a color that is too light.
- Compare against the reference print, not against the section next to it, which may be a different color by design.
The color theory that is actually useful here
Not for mixing — for understanding why the design looks the way it does, which makes you paint it better.
Value does more than color. Value is how light or dark something is, independent of hue. A design reads as three-dimensional because of its light-to-dark structure, not because of its colors. This is why painting dark to light matters, and why a canvas with real darks in it looks more vivid on a wall than one that is uniformly bright.
Complements sharpen each other. Colors opposite on the wheel — orange and blue, red and green, yellow and violet — intensify when placed side by side. It is why autumn scenes look vivid without effort, and why a single warm lamp in a blue night scene carries a whole canvas.
Shadows are not grey or black. In a well-observed design, shadow on snow is blue or violet, shadow on skin is warm. If a pot looks like an odd color on its own, it is usually a shadow color and it will be right in place. Trust the design over your instinct here.
Warm advances, cool recedes. Warm colors come forward and cool ones fall back, which is how a flat canvas suggests distance. It is also why the distant hills in a landscape kit are painted a pale blue-grey that looks wrong in the pot.
Why the pots look wrong and the canvas looks right
This surprises people often enough to be worth stating. Individual premixed colors frequently look muddy, odd or unpleasant on their own. Color is relative — a pale grey-violet is meaningless in isolation and reads as luminous shadow when it sits next to the right neighbours.
The design came from a finished original painting. The relationships were settled before anything was numbered. If a color looks wrong in the pot, paint it anyway.
Common questions
Do I need to mix paint for a paint by numbers kit?
No. The colors are premixed to the design and numbered to match. Mixing only comes up if you run out of a color or choose to go beyond the design.
I have run out of one color. What can I do?
Extra paint sets exist for most designs and are the reliable route. Matching by hand from the other pots is possible but hard to get exact.
Why does one of my colors look wrong?
Premixed shadow and distance colors often look odd alone. Color is relative, and these were chosen to work against their neighbours rather than in isolation.
Does acrylic change color as it dries?
Slightly darker. If you are matching a mixed color, let the test patch dry fully before judging it.